50+ Celebrity Couples Whose Relationship Started as an Affair

[post_page_title]Brad Pitt and Angelina Jolie[/post_page_title]

These celebrities were the envy of many for years. The seemingly perfect couples first met while filming the top-grossing Mr. and Mrs. Smith. In the movie, the two were assassins who were eventually sent to kill each other.

Brad Pitt and Angelina Jolie

It is believed that they first hit it off while filming the movie. At the time of filming, Brad Pitt was still married to Jennifer Anniston for more than five years. Jennifer filed for divorce after the film production was over. Jolie and Brad officially became an item in 2005.

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